Formation of alkyne-bridged ferrocenophanes using ring-closing alkyne metathesis on 1,1’-diacetylenic ferrocenes

Novel alkyne-bridged ferrocenophanes [fc{CO2(CH2)nC≡}2] (2a: n = 2; 2b: n = 3) were synthesized from the corresponding terminal diacetylenic ferrocenes [fc{CO2(CH2)nC≡CH}2] (1a: n = 2; 1b: n = 3) through ring-closing alkyne metathesis (RCAM) utilizing the highly effective molybdenum catalyst [MesC≡M...

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Principais autores:	Celine Bittner, Dirk Bockfeld, Matthias Tamm
格式:	Artigo
语言:	Inglês
出版:	Beilstein-Institut 2019-10-01
丛编:	Beilstein Journal of Organic Chemistry
主题:	alkyne metathesis ferrocene homogeneous catalysis molybdenum terminal alkynes
在线阅读:	https://doi.org/10.3762/bjoc.15.246
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