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Chemoselectively Functionalized Ketoesters by Halogenative C–C Bond Cleavage of Cyclic Diketones

Haloketoesters are synthetic intermediates in various cyclization reactions that facilitate the production of biologically active compounds. Nonetheless, the selective synthesis of dihaloketoesters and trihaloketoesters, which are expected to be highly versatile, presents significant challenges. In...

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Main Authors: Hideyasu China, Nami Kageyama, Hodaka Yatabe, Mihoyo Fujitake, Yusei Matsumoto, Zhihan Jing, Toshifumi Dohi
Format: Artigo
Language:Inglês
Published: MDPI AG 2026-01-01
Series:Molecules
Subjects:
ketoesters
functionalization
halogenation
C–C bond cleavage
cyclic diketone
ring-opening reaction
Online Access:https://www.mdpi.com/1420-3049/31/1/199
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