Base-Mediated Claisen Rearrangement of CF₃-Containing Bisallyl Ethers

We have previously clarified that the strongly electron-withdrawing CF₃ group nicely affected the base-mediated proton shift of CF₃-containing propargylic or allylic alcohols to afford the corresponding α,β-unsaturated or saturated ketones, respectively, which was applied this...

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Autors principals:	Yoko Hamada, Rio Matsunaga, Tomoko Kawasaki-Takasuka, Takashi Yamazaki
Format:	Artigo
Idioma:	Inglês
Publicat:	MDPI AG 2021-07-01
Col·lecció:	Molecules
Matèries:	Claisen rearrangement isomerization trifluoromethyl Cieplak rule
Accés en línia:	https://www.mdpi.com/1420-3049/26/14/4365
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