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Ti Group Metallocene-Catalyzed Synthesis of 1-Hexene Dimers and Tetramers

1-Hexene transformations in the catalytic systems L<sub>2</sub>MCl<sub>2</sub>–XAlBu<sup>i</sup><sub>2</sub> (L = Cp, M = Ti, Zr, Hf; L = Ind, rac-H<sub>4</sub>C<sub>2</sub>[THInd]<sub>2</sub>, M = Zr; X = H, Bu <sup>i</sup>) and [Cp<sub>2</sub>ZrH<sub>2</sub>]<sub>2</sub>-ClAlR<sub>2</sub> activate...

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Principais autores: Pavel V. Kovyazin, Almira Kh. Bikmeeva, Denis N. Islamov, Vasiliy M. Yanybin, Tatyana V. Tyumkina, Lyudmila V. Parfenova
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2021-05-01
Serier:Molecules
Fag:
metallocenes
metal hydrides
dimerization
nuclear magnetic resonance
density functional theory
Online adgang:https://www.mdpi.com/1420-3049/26/9/2775
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