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Quasi-Living Polymerization of Propene with an Isotactic-Specific Zirconocene Catalyst

Propene polymerization with isotactic (iso)-specific C2-symmetric rac-Me2Si(2-Me-Benz(e)-Ind)2ZrCl2 (1) and rac-Me2Si(2-Me-4-Ph-1-Ind)2ZrCl2 (2) were conducted under various conditions for achieving iso-specific living polymerization of propene. When Complex 1 was activated with trialkylaluminum-fre...

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Main Authors: Kei Nishii, Miyuki Murase, Takeshi Shiono
Format: Artigo
Language:Inglês
Published: MDPI AG 2017-05-01
Series:Molecules
Subjects:
isotactic
1-octene
polymerization
propene
quasi-living
zirconocene
Online Access:http://www.mdpi.com/1420-3049/22/5/725
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