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Porphyrins Through the Looking Glass: Spectroscopic and Mechanistic Insights in Supramolecular Chirogenesis of New Self-Assembled Porphyrin Derivatives

The solvent driven aggregation of porphyrin derivatives, covalently linked to a L- or D-prolinate enantiomer, results in the stereospecific formation of species featuring remarkable supramolecular chirality, as a consequence of reading and amplification of the stereochemical information stored in th...

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Principais autores: Manuela Stefanelli, Marco Savioli, Francesca Zurlo, Gabriele Magna, Sandra Belviso, Giulia Marsico, Stefano Superchi, Mariano Venanzi, Corrado Di Natale, Roberto Paolesse, Donato Monti
Format: Artigo
Sprog:Inglês
Udgivet: Frontiers Media S.A. 2020-10-01
Serier:Frontiers in Chemistry
Fag:
porphyrins
circular dichroism
supramolecular chemistry
supramolecular chirogenesis
self-assembly
chirality
Online adgang:https://www.frontiersin.org/article/10.3389/fchem.2020.587842/full
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