Improved Synthesis of Dinuclear [M(μ‐X)(η5‐Cp*)X]2 Precursors for Half‐Sandwich Complexes (M=Rh or Ir; X=Br or I)

Abstract The long‐known dinuclear complexes of the general formula [M(μ‐X)(η5‐Cp*)X]2 (1–4; M=Rh or Ir, X=Br or I; HCp*=pentamethylcyclopentadiene) represent important intermediates for the preparation of biologically (e. g., anticancer or antimicrobial) and catalytically active half‐sandwich rhodiu...

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Principais autores:	Dr. Kamila Petrželová, Dr. Ondřej Bárta, Dr. Renata Héžová, Alžběta Andrýsková, Assoc. Prof. Jan Hošek, Assoc. Prof. Pavel Štarha
Formato:	Artigo
Idioma:	Inglês
Publicado:	Wiley-VCH 2025-09-01
Series:	ChemistryOpen
Assuntos:	Rhodium Iridium Cyclopentadienyl Bromido Iodido
Acceso en liña:	https://doi.org/10.1002/open.202500026
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