Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity

Abstract The effects of halide ligands on the photoluminescence (PL) and photoredox properties were examined on [IrAu12(dppe)5X2]+ (1X; X=Cl, Br, I; dppe=1,2‐bis(diphenylphosphino)ethane). The PL quantum yield was enhanced in the order of 1Cl (67 %)<1Br (75 %)<1I (77 %). The lifetime of the photoexc...

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Autors principals:	Dr. Haru Hirai, Prof. Dr. Shinjiro Takano, Prof. Dr. Shinya Masuda, Prof. Dr. Tatsuya Tsukuda
Format:	Artigo
Idioma:	Inglês
Publicat:	Wiley-VCH 2024-03-01
Col·lecció:	ChemElectroChem
Matèries:	Cluster compounds Gold Halides Luminescence Photoredox catalysis
Accés en línia:	https://doi.org/10.1002/celc.202300669
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