High-pressure synthesis and crystal structure of iron sp 3-carbonate (Fe2[C4O10]) featuring pyramidal [C4O10]4- anions

Abstract The behavior of iron carbonates at high pressures is relevant for geological processes occurring in Earth interiors. Here, cubic iron sp 3-carbonate Fe2[C4O10] was synthesized in diamond anvil cell by reacting Fe2O3 and CO2 at 65(4) GPa and 3000(±500) K, simulating the environment of locali...

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Hlavní autoři:	Valentin Kovalev, Dominik Spahr, Bjoern Winkler, Lkhamsuren Bayarjargal, Lena Wedek, Alena Aslandukova, Anna Pakhomova, Gaston Garbarino, Elena Bykova
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	Nature Portfolio 2025-03-01
Edice:	Communications Chemistry
On-line přístup:	https://doi.org/10.1038/s42004-025-01450-0
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