Regioselective palladium-catalyzed ring-opening reactions of C1-substituted oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylates

Palladium-catalyzed ring-opening reactions of C1 substituted 7-oxanorbornadiene derivatives with aryl iodides were investigated. The optimal conditions for this reaction were found to be PdCl2(PPh3)2, ZnCl2, Et3N and Zn in THF. Both steric and electronic factors played a role in the outcome of the r...

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Autori principali:	Michael Edmunds, Mohammed Abdul Raheem, Rebecca Boutin, Katrina Tait, William Tam
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	Beilstein-Institut 2016-02-01
Serie:	Beilstein Journal of Organic Chemistry
Soggetti:	aryl iodides oxabenzonorbornadiene palladium catalysis regioselectivity ring-opening reactions
Accesso online:	https://doi.org/10.3762/bjoc.12.25
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