Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Iridium Complexes: Synthesis and Asymmetric Catalysis

A new class of bis-cyclometalated iridium(III) catalysts containing two inert cyclometalated 6-<i>tert</i>-butyl-2-phenyl-2<i>H</i>-indazole bidentate ligands or two inert cyclometalated 5-<i>tert</i>-butyl-1-methyl-2-phenylbenzimidazoles is introduced. The coordination sphere is complemented by two...

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Autors principals:	Sebastian Brunen, Yvonne Grell, Philipp S. Steinlandt, Klaus Harms, Eric Meggers
Format:	Artigo
Idioma:	Inglês
Publicat:	MDPI AG 2021-03-01
Col·lecció:	Molecules
Matèries:	cyclometalation chiral-at-metal asymmetric catalysis
Accés en línia:	https://www.mdpi.com/1420-3049/26/7/1822
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