Syntheses of Four Enantiomers of 2,3-Diendo- and 3-Endo-aminobicyclo[2.2.2]oct-5-ene-2-exo-carboxylic Acid and Their Saturated Analogues

Ethyl 2,3-diendo-3-aminobicyclo[2.2.2]oct-5-ene-2-carboxylate ((±)-1) was resolved with O,O'-dibenzoyltartaric acid via diastereomeric salt formation. The efficient synthesis of the enantiomers of 2,3-diendo-3-aminobicyclo[2.2.2]oct-5-ene-2-carboxylic acid ((+)-7 and (–)-7), 3-endo-aminobicyclo[2.2....

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Bibliografische gegevens

Hoofdauteurs:	Márta Palkó, Mikko M. Hänninen, Reijo Sillanpää, Ferenc Fülöp
Formaat:	Artigo
Taal:	Inglês
Gepubliceerd in:	MDPI AG 2013-12-01
Reeks:	Molecules
Onderwerpen:	bicyclic β-amino acid derivatives constrained chiral β-amino acids resolution continuous flow hydrogenations
Online toegang:	http://www.mdpi.com/1420-3049/18/12/15080
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