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Formation of macrocyclic lactones in the Paternò–Büchi dimerization reaction

Furan-2-ylmethyl 2-oxoacetates 1a,b, in which the furan ring and the carbonyl moiety were embedded intramolecularly, were synthesized from commercially available furan-2-ylmethanol and their photochemical reaction (hν > 290 nm) was investigated. Twelve-membered macrocyclic lactones 2a,b with Ci symm...

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Principais autores: Junya Arimura, Tsutomu Mizuta, Yoshikazu Hiraga, Manabu Abe
Formato: Artigo
Idioma:Inglês
Publicado: Beilstein-Institut 2011-02-01
Series:Beilstein Journal of Organic Chemistry
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Acceso en liña:https://doi.org/10.3762/bjoc.7.35
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