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Sandwich-type thorium-substituted phosphotungstate for the catalytic synthesis of aza-heterocycles

A novel sandwich-type thorium-substituted phosphotungstate, [H2N(CH3)2]10[Th(PW11O39)2]·24H2O (ThP2W22), was synthesized and fully characterized. The structure consists of two monolacunary Keggin-type [PW11O39]7− units bridged by an eight-coordinate Th4+ center. ThP2W22 functions as an efficient Lew...

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Библиографические подробности
Главные авторы: Xuejiao Chen, Fuhua Zhang, Jiawei Cao, Zhibin Zhang, Guoping Yang
Формат: Artigo
Язык:Inglês
Опубликовано: Tsinghua University Press 2026-06-01
Серии:Polyoxometalates
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Online-ссылка:https://www.sciopen.com/article/10.26599/POM.2026.9140121
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