Reactivity umpolung of the cycloheptatriene core in hexa(methoxycarbonyl)cycloheptatriene

A reactivity umpolung approach for the derivatization of cycloheptatrienes was extended to hexa(methoxycarbonyl)cycloheptatriene, which forms the corresponding anion reactive towards electrophiles. Despite the presence of four potential reactive sites, the reactions mainly involve the initial electr...

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Главные авторы:	Dmitry N. Platonov, Alexander Yu. Belyy, Rinat F. Salikov, Kirill S. Erokhin, Yury V. Tomilov
Формат:	Artigo
Язык:	Inglês
Опубликовано:	Beilstein-Institut 2026-01-01
Серии:	Beilstein Journal of Organic Chemistry
Предметы:	azo shift cascade reactions cycloheptatriene relief of antiaromaticity umpolung
Online-ссылка:	https://doi.org/10.3762/bjoc.22.2
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