Síntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréia Synthesis of [Pd(dmba)(N3)(PPh3)] and its use in catalytic processes involving the reductive n-carbonylation of nitroarenes to carbamates and in the synthesis of urea derivatives

<abstract language="eng">This work deals with the use of the cyclometallated compound [Pd(dmba)(N3)(PPh3)] in homogeneous catalytic processes comprising the reductive N-carbonylation of nitrobenzene and p-nitrotoluene to ethyl-phenylcarbamate and ethyl-4-methylphenylcarbamate, respectively. The cycl...

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Principais autores:	Antonio Carlos Fávero Caires, Antonio Eduardo Mauro, Antonio Carlos Moro, Alexandre de Oliveira Legendre, Sandra Regina Ananias
Formato:	Artigo
Idioma:	Inglês
Publicado:	Sociedade Brasileira de Química 2006-07-01
Series:	Química Nova
Assuntos:	cyclopalladated compound homogeneous catalytic process reductive N-carbonylation
Acceso en liña:	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000400022
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