Regioselective Mercury(I)/Palladium(II)-Catalyzed Single-Step Approach for the Synthesis of Imines and 2-Substituted Indoles

An efficient synthesis of ketimines was achieved through a regioselective Hg(I)-catalyzed hydroamination of terminal acetylenes in the presence of anilines. The Pd(II)-catalyzed cyclization of these imines into the 2-substituted indoles was satisfactorily carried out by a C-H activation. In a single...

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Principais autores:	Rsuini U. Gutiérrez, Mayra Hernández-Montes, Aarón Mendieta-Moctezuma, Francisco Delgado, Joaquín Tamariz
Formato:	Artigo
Idioma:	Inglês
Publicado em:	MDPI AG 2021-07-01
Colecção:	Molecules
Assuntos:	mercury(I)-catalyzed alkyne hydroamination imines Pd-catalyzed oxidative cyclization one-pot indole synthesis
Acesso em linha:	https://www.mdpi.com/1420-3049/26/13/4092
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