Crystal structure of an unknown tetrahydrofuran solvate of tetrakis(μ3-cyanato-κ3N:N:N)tetrakis[(triphenylphosphane-κP)silver(I)]

In the title compound, [{[(C6H5)3P]Ag}4{NCO}4], a distorted Ag4N4-heterocubane core is set up by four AgI ions being coordinated by the N atoms of the cyanato anions in a μ3-bridging mode. In addition, a triphenylphosphine ligand is datively bonded to each of the AgI ions. Intramolecular Ag...Ag dis...

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Bibliografische gegevens

Hoofdauteurs:	Peter Frenzel, Dieter Schaarschmidt, Alexander Jakob, Heinrich Lang
Formaat:	Artigo
Taal:	Inglês
Gepubliceerd in:	International Union of Crystallography 2015-10-01
Reeks:	Acta Crystallographica Section E: Crystallographic Communications
Onderwerpen:	crystal structure silver(I) cyanate ligand phosphine ligand Ag4N4 heterocubane SQUEEZE procedure
Online toegang:	http://scripts.iucr.org/cgi-bin/paper?S2056989015017636
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