Effect of substrate and catalyst chirality on the diastereoselective epoxidation of R-(+)-limonene with manganese(III) salen complexes

The asymmetric epoxidation of R-(+)-limonene in the presence of the Jacobsen´s catalyst in its chiral and achiral either homogeneous or heterogeneous (immobilized on Al-MCM-41) forms was studied using in situ generated dimethyldioxirane as oxidizing agent. It was found that the catalytic activity o...

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Detalhes bibliográficos

Principais autores:	Juliana Reyes, Jairo Antonio Cubillos, Aída Luz Villa, Consuelo Montes de Correa
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Universidad de Antioquia 2013-07-01
coleção:	Revista Facultad de Ingeniería Universidad de Antioquia
Assuntos:	R-( )-limonene enantiomerically pure epoxides asymmetric synthesis manganese (III) salen complexes optically active catalysts achiral catalyst
Acesso em linha:	https://revistas.udea.edu.co/index.php/ingenieria/article/view/16005
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