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Organocatalytic Asymmetric Peroxidation of γ,δ-Unsaturated β-Keto Esters—A Novel Route to Chiral Cycloperoxides

A methodology for the asymmetric peroxidation of γ,δ-unsaturated β-keto esters is presented. Using a cinchona-derived organocatalyst, the target δ-peroxy-β-keto esters were obtained in high enantiomeric ratios of up to 95:5. Additionally, these δ-peroxy esters can be readily reduced to chiral δ-hydr...

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Principais autores: Mary C. Hennessy, Hirenkumar Gandhi, Timothy P. O’Sullivan
פורמט: Artigo
שפה:Inglês
יצא לאור: MDPI AG 2023-05-01
סדרה:Molecules
נושאים:
cycloperoxides
organocatalysis
δ-peroxy-β-keto esters
δ-hydroxy-β-keto esters
1,2-dioxolanes
גישה מקוונת:https://www.mdpi.com/1420-3049/28/11/4317
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