Silver-catalyzed oxidative alkylation/alkynylation of 1,4-enynyl-3-ols with alkylbromides through radical 1,2-alkynyl migration

In this study, we have described a novel reaction between 1,4-enynyl-3-ols and alkyl bromides. The reaction was carried out in the presence of Ag2O, following a free radical 1,2-alkynyl migration pathway, which was confirmed through control experiments. This methodology offers several advantages, in...

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Bibliografische Detailangaben

Hauptverfasser:	De Chen, Nianqi Zhang, Qiuju Liang, Wei Deng, Zhiyi Xiao, Wanrong Dong, Jiannan Xiang
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	Elsevier 2024-01-01
Schriftenreihe:	Catalysis Communications
Schlagworte:	1,2-Alkynyl migration Silver-catalysis 1,4-Enynyl-3-ols Alkylbrmodes Alkynylation/alkylation
Online-Zugang:	http://www.sciencedirect.com/science/article/pii/S1566736723002261
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