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Asymmetric Titanium-Catalyzed Cyclopropanation of Nitriles with Grignard Reagents

Abstract The titanium-catalyzed asymmetric cyclopropanation of cyanoesters­ with Grignard reagents was investigated for the first time. Particularly, the study of the efficiency of Taddol-based titanium complexes­ has shown that the prior preparation of Taddol titanium complexes was not required and...

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Principais autores: Julien Caillé, Paul Setzer, Fabien Boeda, Morwenna S. M. Pearson-Long, Philippe Bertus
Format: Artigo
Sprog:Inglês
Udgivet: Georg Thieme Verlag KG 2018-01-01
Serier:SynOpen
Fag:
cyclopropanes
enantioselectivity
grignard reagents
nitriles­
spiro compounds
titanium
Online adgang:http://www.thieme-connect.de/DOI/DOI?10.1055/s-0036-1591933
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