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Hydrogen bonds and π–π interactions in two new crystalline phases of methylene blue

Two unprecedented solid phases involving the 3,7-bis(dimethylamino)phenothiazin-5-ium cation, i.e. methylene blue (MB+), have been obtained and structurally characterized. In the crystals of 3,7-bis(dimethylamino)phenothiazin-5-ium chloride dihydrate, C16H18N3S+·Cl−·2H2O (I) and 3,7-bis(dimethylamin...

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Principais autores: Stefano Canossa, Giovanni Predieri, Claudia Graiff
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2018-05-01
coleção:Acta Crystallographica Section E: Crystallographic Communications
Assuntos:
crystal structure
methylene blue
chloride
bisulfite
hydrogen bonding
π–π interactions
Hirshfeld surface analysis
Acesso em linha:http://scripts.iucr.org/cgi-bin/paper?S2056989017017881
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