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Calcium coordination polymer containing dimethylphosphate ligands and exhibiting nucleating properties towards α and Β crystal polymorphs of isotactic polypropylene

Abstract The synthesis, structure and thermal properties of a one-dimensional coordination polymer based on calcium bis(dimethylphosphate) (CaDMP) are reported. The rod-like particles of CaDMP crystallized from water in a monoclinic space group P21/c, and contained Ca[O2P(OCH3)2]2 polymeric chains c...

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Principais autores: Maciej Dębowski, Mateusz Kullas, Krystyna Czaja, Beata Sacher-Majewska, Marcin Bączek, Maciej Dranka, Andrzej Ostrowski, Zbigniew Florjańczyk
Format: Artigo
Sprog:Inglês
Udgivet: Nature Portfolio 2025-05-01
Serier:Scientific Reports
Fag:
Hybrid polymer
Calcium diorganophosphate
Isotactic polypropylene
Crystallization
Nucleating agent
Polymer composite
Online adgang:https://doi.org/10.1038/s41598-025-99757-4
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