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Enantioselective Solvent-Free Synthesis of 3-Alkyl-3-hydroxy-2-oxoindoles Catalyzed by Binam-Prolinamides

BINAM-prolinamides are very efficient catalyst for the synthesis of non-protected and N-benzyl isatin derivatives by using an aldol reaction between ketones and isatins under solvent-free conditions. The results in terms of diastereo- and enantioselectivities are good, up to 99% de and 97% ee, and h...

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Principais autores: Abraham Bañn-Caballero, Jesús Flores-Ferrándiz, Gabriela Guillena, Carmen Nájera
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI AG 2015-07-01
coleção:Molecules
Assuntos:
isatin
aldol
enantioselectivity
solvent-free
prolinamide
supported catalyst
Acesso em linha:http://www.mdpi.com/1420-3049/20/7/12901
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