Stabilization of {Ag<sub>20</sub>(S<sup>t</sup>Bu)<sub>10</sub>} and {Ag<sub>19</sub>(S<sup>t</sup>Bu)<sub>10</sub>} Toroidal Complexes in DMSO: HPLC-ICP-AES, PL, and Structural Studies
The presence of DMSO provides a unique ability to stabilize silver toroidal complexes in the direct reaction between AgS<sup>t</sup>Bu and AgNO<sub>3</sub> at 80 °C. Slow cooling results in large crystals of [NO<sub>3</sub>@Ag<sub>19.2</sub>(S<sup>t</sup>Bu)<sub>10</sub>(DMSO)<sub>5.2</sub>(NO<sub>3...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
MDPI AG
2022-11-01
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| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/10/12/225 |
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