The Enigma of Sponge-Derived Terpenoid Isothiocyanate–Thiocyanate Pairs: A Biosynthetic Proposal

The co-occurrence of rare terpenoid thiocyanates (R-SCN), structurally similar to their more common isothiocyanate isomers (R-NCS), poses an enigma: how does the accepted path, terpenyl cation R⁺ → R-NC → R-NCS, accommodate R-SCN? The mystery can now be rationalized by the consideration o...

Ausführliche Beschreibung

Bibliografische Detailangaben

1. Verfasser:	Tadeusz F. Molinski
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	MDPI AG 2025-05-01
Schriftenreihe:	Marine Drugs
Schlagworte:	alkyl isothiocyanate alkyl thiocyanate farnesyl pyrophosphate geranylgeranyl pyrophosphate malaria marine natural product
Online-Zugang:	https://www.mdpi.com/1660-3397/23/5/220
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