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(S)-3-Dimethylamino-2-{(4S,5R)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}-2-hydroxypropanoic acid

The Kiliani reaction on 1-deoxy-(N,N-dimethylamino)-d-fructose, itself readily available from reaction of dimethylamine and d-glucose, proceeded to give access to the title β-sugar amino acid, C15H27NO7. X-ray crystallography determined the stereochemistry at the newly formed chiral center. The...

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Principais autores: Sarah F. Jenkinson, David J. Hotchkiss, Andrew R. Cowley, George W. J. Fleet, David J. Watkin
Formato: Artigo
Idioma:Inglês
Publicado: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Acceso en liña:http://scripts.iucr.org/cgi-bin/paper?S1600536807066676
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