Selective cleavage of Csp3–N bonds in aliphatic tertiary amines enabled by difluorocarbene to access esters and thioethers
Presented herein is a series of C–X (X = O, S) couplings for the synthesis of esters and thioethers via difluorocarbene-promoted selective Csp3–N bond cleavage between tertiary amines and carboxylic acids or thiols. In those reactions, difluorocarbene plays an important role for generating quatern...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
KeAi Communications Co. Ltd.
2025-11-01
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| Schriftenreihe: | Green Synthesis and Catalysis |
| Schlagworte: | |
| Online-Zugang: | http://www.sciencedirect.com/science/article/pii/S2666554924000528 |
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