Synthesis of α-tertiary allylsilanes by palladium-catalyzed hydrosilylation of 1,1-disubstituted allenes
We herein report an effective hydrosilylation of 1,1-disubstituted allenes with a palladium catalyst modified by a monophosphorus ligand, leading to a series of α-tertiary allylsilanes in high yields and exceptional regioselectivities. The employment of BI-DIME is essential for the high reactivities...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
KeAi Communications Co. Ltd.
2020-11-01
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| coleção: | Green Synthesis and Catalysis |
| Assuntos: | |
| Acesso em linha: | http://www.sciencedirect.com/science/article/pii/S2666554920300272 |
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