Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctenedione

The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a bicyclo[4.2.0]octane system using an acyloin reaction on the trans-2,3-dicarboethoxy-1,2,3,4-tetrahydronaphthalene 1 in the presence of trimethylchlorosilane (TMCS). The two intermediates of this reac...

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Principais autores:	Adeleh Moshtaghi Zenouz, Saeed Abolghassemi Fakhri
Formato:	Artigo
Idioma:	Inglês
Publicado em:	MDPI AG 2002-11-01
Colecção:	Molecules
Assuntos:	7 8-benzocyclooctenedione acyloin reaction conrotatory electrocyclic ring opening fragmentation of bicyclo[ 4.2.0 ]octane systems eight-membered rings
Acesso em linha:	http://www.mdpi.com/1420-3049/7/11/801/
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