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For a Correct Application of the CD Exciton Chirality Method: The Case of Laucysteinamide A

The circular dichroism (CD) exciton chirality method (ECM) is a very popular approach for assigning the absolute configuration (AC) of natural products, thanks to its immediacy and ease of application. The sign of an exciton couplet (two electronic CD bands with opposite sign and similar intensity)...

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Autore principale: Gennaro Pescitelli
Natura: Artigo
Lingua:Inglês
Pubblicazione: MDPI AG 2018-10-01
Serie:Marine Drugs
Soggetti:
electronic circular dichroism
absolute configuration
molecular conformation
electric transition dipole moment
exciton coupling
TDDFT calculations
Accesso online:http://www.mdpi.com/1660-3397/16/10/388
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