Synthesis and Enzymatic Conversion of Amino Acids Equipped with the Silanetriol Functionality: A Prelude to Silicon Biodiversification

Abstract Synthetic routes are reported for the three analogues of the simplest L‐2‐amino‐dicarboxylic acids, aspartate, glutamate, and aminoadipate, in which the silanetriol group (Si(OH)3) replaces the distal carboxyl group (CO2H). Direct access to the silanetriol amino acids relied either on catal...

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Detalhes bibliográficos

Principais autores:	Dr. Jade Dussart‐Gautheret, Dr. Julie Rivollier, Dr. Cédric Simon, Dr. Alessandro De Simone, Dr. Jérôme Berthet, Prof. Stéphanie Delbaere, Régina Maruchenko, Claire Troufflard, Dr. Denis Lesage, Dr. Yves Gimbert, Dr. Gilles Lemière, Dr. Philippe Marlière, Prof. Louis Fensterbank
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Wiley-VCH 2023-11-01
coleção:	ChemistryEurope
Assuntos:	aminotransferases cluster compounds hydrosilylation silanetriols xenobiology
Acesso em linha:	https://doi.org/10.1002/ceur.202300058
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