On the Aromaticity and <sup>13</sup>C-NMR Pattern of Pentagonal-Pyramidal Hexamethylbenzene Dication [C<sub>6</sub>(CH<sub>3</sub>)<sub>6</sub>]<sup>2+</sup>: A {C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>}<sup>−</sup>–{CCH<sub>3</sub>}<sup>3+</sup> Aggregate
The experimentally characterized hexamethylbenzene dication C<sub>6</sub>(CH<sub>3</sub>)<sub>6</sub><sup>2+</sup> shows a pentagonal-pyramidal structure involving a carbon-capped five-membered ring. The structural characterization of this hypercoordination (or hypervalency) gives rise if the aromat...
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| Principais autores: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
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MDPI AG
2021-11-01
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| coleção: | Chemistry |
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| Acesso em linha: | https://www.mdpi.com/2624-8549/3/4/97 |
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