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THE SYNTHESIS AND STUDY OF TETRANUCLEAR CLUSTER [Fe4O2(CCl3COO)8(THF)2(DMF)(H2O)]⋅THF

The novel bis(μ3-oxo) tetranuclear trichloracetate cluster, [Fe4O2(CCl3COO)8(THF)2(DMF)(H2O)]⋅THF (1), has been synthesised and subsequently characterised by X-ray structure analysis, magnetic measurements and infra red (IR). The structure of cluster is “butterfly” type. The Fe···Fe separation has t...

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Principais autores: Denis Prodius, Valeriu Mereacre, Sergiu Shova, Maria Gdaniec, Yurii Simonov, Lorenzo Sorace, Andrea Caneschi, Nicolae Stanica, Ion Geru, Constantin Turta
Formato: Artigo
Idioma:Inglês
Publicado em: Academy of Sciences of Moldova, Institute of Chemistry 2006-06-01
coleção:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Assuntos:
Antiferromagnetic exchange
Acesso em linha:http://www.cjm.asm.md/sites/default/files/article_files/AA-0005_077.pdf
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