TMSBr-mediated solvent- and work-up-free synthesis of α-2-deoxyglycosides from glycals

The thio-additions of glycals were efficiently promoted by a stoichiometric amount of trimethylsilyl bromide (TMSBr) to produce S-2-deoxyglycosides under solvent-free conditions in good to excellent yields. In addition, with triphenylphosphine oxide as an additive, the TMSBr-mediated direct glycosyl...

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Detalhes bibliográficos

Principais autores:	Mei-Yuan Hsu, Yi-Pei Liu, Sarah Lam, Su-Ching Lin, Cheng-Chung Wang
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Beilstein-Institut 2016-08-01
coleção:	Beilstein Journal of Organic Chemistry
Assuntos:	2-deoxyglycosides glycals trimethylsilyl bromide (TMSBr) triphenylphosphine oxide (TPPO)
Acesso em linha:	https://doi.org/10.3762/bjoc.12.164
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