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Reduction of the Diazo Functionality of α-Diazocarbonyl Compounds into a Methylene Group by NH<sub>3</sub>BH<sub>3</sub> or NaBH<sub>4</sub> Catalyzed by Au Nanoparticles

Supported Au nanoparticles on TiO<sub>2</sub> (1 mol%) are capable of catalyzing the reduction of the carbene-like diazo functionality of α-diazocarbonyl compounds into a methylene group [C=(N<sub>2</sub>) → CH<sub>2</sub>] by NH<sub>3</sub>BH<sub>3</sub> or NaBH<sub>4</sub> in methanol as solvent....

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Kaydedildi:
Asıl Yazarlar: Marios Kidonakis, Manolis Stratakis
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: MDPI AG 2021-01-01
Seri Bilgileri:Nanomaterials
Konular:
α-diazocarbonyl compounds
transfer hydrogenation
boron hydrides
heterogeneous catalysis
supported Au nanoparticles
Online Erişim:https://www.mdpi.com/2079-4991/11/1/248
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