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Assembly of Imidazolyl-Substituted Nitronyl Nitroxides into Ferromagnetically Coupled Chains

New nitronyl nitroxides, namely, 2-(4,5-dimethylimidazol-2-yl)- and 2-(4,5-dichloroimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1<i>H</i>-imidazol-3-oxide-1-oxyl, were prepared in crystalline form. According to single-crystal X-ray data, intra- and intermolecular hydrogen bonds are formed between...

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Main Authors: Vasily Romanov, Irina Bagryanskaya, Nina Gritsan, Dmitry Gorbunov, Yulia Vlasenko, Mehman Yusubov, Elena Zaytseva, Dominique Luneau, Evgeny Tretyakov
Format: Artigo
Language:Inglês
Published: MDPI AG 2019-04-01
Series:Crystals
Subjects:
nitronyl nitroxides
imidazole
crystal structure
hydrogen bonding
exchange interaction
density functional theory
Online Access:https://www.mdpi.com/2073-4352/9/4/219
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