Synthesis and characterization of [(CO)4FeL-L] and [(CO)4FeL-LFe(CO)4] wherein L-L is N(CH2CH2)3N and also P(NMeNMe)3P in the latter complex: single crystal X-ray molecular structure of [Fe(CO)4DABCO]
Herein we report the syntheses and characterization of the novel title mono- and dinuclear compounds from pentacarbonyliron. They were obtained in a stepwise manner by UV irradiation of [Fe(CO)5] with the appropriate ligand in THF and were characterized by ¹H, 13C, 13C{¹H} 31P and 31P{¹H} NMR spectr...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Sociedade Brasileira de Química
2003-01-01
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| Serie: | Journal of the Brazilian Chemical Society |
| Soggetti: | |
| Accesso online: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100012 |
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