Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones
Stereodivergent construction of adjacent quaternary-quaternary stereocenters remains a formidable synthetic challenge. Here, the authors report a nickel-catalyzed enantioselective dearomatization Claisen rearrangement leading to vicinal all-carbon stereocentres and apply it to the stereodivergent sy...
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| Autores principales: | , , , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Nature Portfolio
2018-05-01
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| Colección: | Nature Communications |
| Acceso en línea: | https://doi.org/10.1038/s41467-018-04123-w |
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