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Control of Multiple Stereogenic Elements in Diaryl Ethers

We report a chiral phosphoric acid (CPA)‐catalyzed desymmetrizing aminoacetalization strategy of proaxially chiral dialdehydes that enables the construction of diaryl ethers bearing both central and axial chirality. This organocatalytic atroposelective heteroannulation proceeds under mild conditions...

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Hoofdauteurs: Abdelati Naghim, Pandidurai Solai, Michel Giorgi, Jean‐Valère Naubron, Stéphane Humbel, Radhika Gupta, Jean Rodriguez, Olivier Chuzel, Gaëlle Chouraqui, Damien Bonne
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Wiley-VCH 2026-03-01
Reeks:ChemistryEurope
Onderwerpen:
atropisomers
chiral phosphoric acids
diaryl ethers
diastereomerization barrier
multichirality
Online toegang:https://doi.org/10.1002/ceur.70257
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