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Theoretical Studies on the Reaction Mechanism for the Cycloaddition of Zwitterionic π-Allenyl Palladium Species: Substrate-Controlled Isomerization

Zwitterionic π-allenyl palladium species are newly developed intermediates. A substrate-controlled step existed in the cycloaddition of zwitterionic π-allenyl palladium species with tropsulfimides or tropones. With the assistance of previously experimental studies, zwitterionic allenyl/propargyl pal...

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Principais autores: Yongjie Long, Jiahao Shen, Min Shi, Yin Wei
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2024-12-01
Serier:Molecules
Fag:
mechanistic studies
palladium catalyzed
zwitterionic π-allenyl palladium species
cycloaddition
substrate-controlled reaction
DFT calculation
Online adgang:https://www.mdpi.com/1420-3049/30/1/103
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