Mechanistic insight into C−S bond construction using CO2 as a carbon source: Synthesis of benzothiazoles from 2-aminothiophenols in imidazolium acetate
DFT calculations on synthesis of benzothiazoles via cyclization of 2-aminothiophenols with CO2 and triethoxysilane have revealed a novel mechanism that fundamentally differs from previously proposed mechanisms. In this new mechanism, the acetate anion plays a pivotal role in both stages of the react...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Elsevier
2024-07-01
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| coleção: | Journal of CO2 Utilization |
| Assuntos: | |
| Acesso em linha: | http://www.sciencedirect.com/science/article/pii/S2212982024002099 |
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