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Substitution reactivity of [Mo3(µ3-O)(µ3-CCH3)(µ-O2CCHCl2)6(CH3OH)3]O2CCHCl2 (Mo3) and the crystallization of a deca-molybdenum cluster [Mo10O10(μ3-O)8(μ-O)8(py)8](py)2 from Mo3 in pyridine

By heating the trinuclear acetate-bridged molybdenum cluster, [Mo3(µ3-O)(µ3-CCH3)(µ-O2CCH3)6(H2O)3]+ in neat dichloroacetic acid for 4 h (T = 115 °C), a new trinuclear molybdenum cluster with chemical formula [Mo3(µ3-O)(µ3-CCH3)(µ-O2CCHCl2)6(CH3OH)3]+ (abbreviated as Mo3) was synthesized. After prec...

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Principais autores: Richard Brookins, James C. Fettinger, Jacqueline R. Houston
Format: Artigo
Sprog:Inglês
Udgivet: Elsevier 2024-06-01
Serier:Results in Chemistry
Fag:
Trinuclear molybdenum cluster
Ligand substitution
Deca-molybdenum cluster
Online adgang:http://www.sciencedirect.com/science/article/pii/S2211715624003151
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