Hypervalent iodine(III)-mediated decarboxylative acetoxylation at tertiary and benzylic carbon centers
The decarboxylative acetoxylation of carboxylic acids using a combination of PhI(OAc)2 and I2 in a CH2Cl2/AcOH mixed solvent is reported. The reaction was successfully applied to two types of carboxylic acids containing an α-quaternary and a benzylic carbon center under mild reaction conditions. The...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2018-05-01
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| coleção: | Beilstein Journal of Organic Chemistry |
| Assuntos: | |
| Acesso em linha: | https://doi.org/10.3762/bjoc.14.92 |
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