Syntheses and crystal structures of (R,R)- and (S,S)-bis(acetonitrile-κN)[N,N′-dimethyl-N,N′-bis(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ4N]iron(II) bis(hexafluoroantimonate)

Two enantiomeric non-heme iron complexes [Fe(R,R-BPMCN)(CH3CN)2](SbF6)2 and [Fe(S,S-BPMCN)(CH3CN)2](SbF6)2 (BPMCM = N,N′-dimethyl-N,N′-bis(pyridin-2-ylmethyl)-cyclohexane-1,2-diamine, C22H28N4) were obtained in parallel syntheses starting from the enantiomerically pure R,R and S,S BPMCN ligands. The...

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Ngā kaituhi matua:	Yurii S. Bibik, Iryna M. Yulakh, Svitlana V. Shishkina, Dmytro M. Khomenko, Roman O. Doroshchuk, Ilona V. Raspertova, Rostyslav D. Lampeka
Hōputu:	Artigo
Reo:	Inglês
I whakaputaina:	International Union of Crystallography 2024-12-01
Rangatū:	Acta Crystallographica Section E: Crystallographic Communications
Ngā marau:	crystal structure x-ray crystallography non-heme iron catalysts
Urunga tuihono:	https://journals.iucr.org/paper?S2056989024011307
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