Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions

The Pd–benzothiazol-2-ylidene complex I was found to be a chemoselective catalyst for the Tsuji–Trost allylation of active methylene compounds carried out under neutral conditions and using carbonates as allylating agents. The proposed protocol consists in a simplified procedure adopting an in situ...

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Bibliografiske detaljer

Principais autores:	Antonio Monopoli, Pietro Cotugno, Carlo G. Zambonin, Francesco Ciminale, Angelo Nacci
Format:	Artigo
Sprog:	Inglês
Udgivet:	Beilstein-Institut 2015-06-01
Serier:	Beilstein Journal of Organic Chemistry
Fag:	active methylene compounds allylic carbonates Pd–benzothiazol-2-ylidene complex Tsuji–Trost allylation
Online adgang:	https://doi.org/10.3762/bjoc.11.111
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