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Ti(O-<i>i</i>Pr)<sub>4</sub>-EtMgBr-Catalyzed Reaction of Dialkyl-Substituted Alkynes with Et<sub>2</sub>Zn

For the first time, the Ti(O-<i>i</i>Pr)<sub>4</sub>-EtMgBr carbozincation of dialkyl-substituted alkynes with Et<sub>2</sub>Zn was carried out. It was found that the reaction of 1,2-disubstituted alkynes (5-decyne, 4-octyne, 3-hexyne) with Et<sub>2</sub>Zn is accompanied by the regioselective forma...

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Autors principals: Azat M. Gabdullin, Oleg S. Mozgovoj, Rita N. Kadikova, Ilfir R. Ramazanov, Usein M. Dzhemilev
Format: Artigo
Idioma:Inglês
Publicat: MDPI AG 2021-11-01
Col·lecció:Chemistry Proceedings
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Accés en línia:https://www.mdpi.com/2673-4583/8/1/61
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