Synthese von 5-(Dialkylamino)-5-X-pentadienalen aus 'Push-Pull'-Eninen
5-Aminopent-2-ene-4-inals 1 are easily available by Pd(0)-catalyzed coupling of stannyl ynamines 6 or silyl ynamines 7 with 3-iodoacroleine. They react nearly quantitatively with acids like HCl or AcOH to give 5-amino-5-X-pentadienals 2, which are of interest in view of a postulated rearra...
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| Principais autores: | , |
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| Format: | Artigo |
| Sprog: | Alemão |
| Udgivet: |
Swiss Chemical Society
1995-03-01
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| Serier: | CHIMIA |
| Online adgang: | https://www.chimia.ch/chimia/article/view/2462 |
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