Platinum-containing isopolytungstates: [Pt3W11O41]6.4− with a linear {Pt3O12} triad, [PtII2W5O18((CH3)2AsO2)2]4− and [PtIII2W5O18((CH3)2AsO2)4]4− featuring direct Pt–Pt bonds

The platinum-containing isopolytungstates [Pt3W11O41]6.4− (Pt3W11), [PtII2W5O18((CH3)2AsO2)2]4− (PtII2W5), and [PtIII2W5O18((CH3)2AsO2)4]4− (PtIII2W5) were synthesized in aqueous media and characterized via single-crystal X-ray diffraction and multinuclear (195Pt, 13C, and 1H) nuclear magnetic reson...

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Detalhes bibliográficos

Principais autores:	Jiayao Zhang, Saurav Bhattacharya, Mahmoud Elcheikh Mahmoud, Talha Nisar, Khaoula Merimi, Xavier López, Josep M. Poblet, Veit Wagner, Ulrich Kortz
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Tsinghua University Press 2025-12-01
Colecção:	Polyoxometalates
Assuntos:	polyoxometalates platinum pt–pt bond hydrogenation catalysis mixed-valence compounds quantum mechanical calculations
Acesso em linha:	https://www.sciopen.com/article/10.26599/POM.2025.9140107
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